Geralt's first real armor is a studded leather jacket given to him by Vesemir towards the end of the prologue. It can later be upgraded to the Excellent leather jacket. It can only be sold to human blacksmiths. This jacket can be purchased from Mael on Rhundurin Square in Vergen during Chapter II.
The Blasphemer's Outfit - The Witcher 2 Guide - IGN, the witcher 2
Excellent leather jacket, Witcher Wiki
Studded leather jacket, Witcher Wiki
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Light leather jacket, Witcher Wiki
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Warrior's Leather Jacket - The Witcher 3 Guide - IGN